Processing Invoices and Receipts for National Account

I am trying to process invoices and receipts in Accounts Receivable for a National Account (main account and not a member account), but I get the error that "Customer number XXXX  does not exist". I was under the impression that this is possible and that this is what the User Guide says as per this extract:

  • Accept a single payment from a company and apply it to outstanding invoices for all its branches.
  • Send invoices and statements to the head office, and send orders to the individual branches.

How is this supposed to work? Isn't it possible to transact with the National Account directly?